Identification

Title

ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20140816_2-Methyl-3-buten-1-ol/Methyl nitrite/10102-44-0/OZONE_Hydroxyl radical_No Seed_Dry

Abstract

Goals: This experiment was done to react 2-Methyl-3-buten-1-ol (231 MBO) with ozone to produce the Hydroxymethylpropanal (HMPR). After oxidizing HMPR with OH in the high NO2 condition, we get the HMPR-PAN (or the peroxynitrate of HMPR). This is analogous to MPAN except it has an OH at the 1-position and no double bond, so that when OH abstracts a hydrogen from HMPR-PAN, it makes the exact same alkyl radical as OH addition to MPAN. The only difference is that the alkyl radical from OH + HMPR-PAN is not created with excess energy, compared to OH addition radicals. Thus...the thermalized radical from HMPR-PAN is not hypothesized to have enough energy to form HMML, and therefore wont form secondary organic aerosol (SOA). Summary: The reaction did not produce any significant amounts of SOA from the OH+HMPR-PAN reaction. Therefore the hypothesis is validated, that the alkyl radical of MPAN +OH goes to HMML because it is formed with excess energy through OH addition. We showed the exact same alkyl radical with less energy will add O2 instead of decomposing to HMML. Organization: Caltech Atmospheric Chamber Lab Affiliation: California Institute of Technology, Pasadena, CA Chamber: Near/Far Bag 2012-2015 (Tran) Experiment Category: Gas phase chemical reaction, Aerosol formation Oxidant: Hydroxyl radical Reactants: 2-Methyl-3-buten-1-ol, Methyl nitrite, 10102-44-0, OZONE Reaction Type: Photooxidation Relative Humidity: 4 Temperature: 25 Pressure: 750 Torr

Resource type

dataset

Resource locator

https://gdex.ucar.edu/dataset/id/6e55fff5-faff-486a-aabb-ff151137b975.html

protocol: https

applicationProfile: browser

name: ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20140816_2-Methyl-3-buten-1-ol/Methyl nitrite/10102-44-0/OZONE_Hydroxyl radical_No Seed_Dry

description: Metadata Link

function: download

Unique resource identifier

code

codeSpace

Dataset language

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

Keywords

Keyword set

keyword value

Dataset

originating controlled vocabulary

title

reference date

date type

revision

effective date

2014-10-16

Keyword set

keyword value

EARTH SCIENCE > ATMOSPHERE > AEROSOLS

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Keyword set

keyword value

In Situ/Laboratory Instruments > Chemical Meters/Analyzers

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2014-08-16

End position

2014-08-16

Dataset reference date

date type

publication

effective date

2023-08-23

date type

modified

effective date

2023-08-23

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

Compressed Archive File (application/zip)

version of format

Constraints related to access and use

Constraint set

Use constraints

Creative Commons Attribution 4.0 International License.

Limitations on public access

These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

Responsible organisations

Responsible party

organisation name

Caltech Atmospheric Chamber

email address

wkong@caltech.edu

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

UCAR/NCAR - GDEX

email address

gdex@ucar.edu

responsible party role

pointOfContact

Metadata date

2023-08-23T02:25:46-06:00

Metadata language