Identification

Title

ICARUS Chamber Experiment: Ziemann_20160603_Methyl nitrite/Nitric oxide/5-Undecanol_Hydroxyl radical_DOS

Abstract

Goals: Determine SOA yield of OH radical oxidation of the VOC Summary: Experiments were conducted in an 8.0 m3 FEP Teflon environmental chamber in Boulder, CO, that was filled with clean, dry air [<5 ppb of hydrocarbons and <1% relative humidity (RH)] from two Aadco clean air systems and operated at ambient temperature (?23 °C) and pressure (?630 Torr). The VOC was added to the chamber by evaporating a measured amount of the compound from a heated glass bulb into a stream of ultrahigh-purity (UHP) N2. Approximately 200 ?g m?3 dioctyl sebacate (DOS) seed particles in UHP N2 were added from an evaporation?condensation apparatus. Known amounts of methyl nitrite and NO were prepared on a vacuum manifold using a calibrated glass bulb and absolute pressure gauge and then flushed into the chamber with UHP N2. Reactions were initiated by turning on blacklights that covered two walls of the chamber at 50% intensity (JNO2 = 0.37 h?1) for one hour. Photolysis of methyl nitrite created OH radicals with an average concentration of 4 × 107 molecules cm?3, as determined from the measured decay of the VOC and estimated OH reaction rate constants. The VOC, methyl nitrite, and NO concentrations were 1, 5, and 5 ppm. Organization: Ziemann Lab Affiliation: University of Colorado, Boulder, Boulder, CO, USA Chamber: Janet (Chamber 1) Experiment Category: Gas phase chemical reaction, Photolysis, any phase, Aerosol formation Oxidant: Hydroxyl radical Reactants: Methyl nitrite, Nitric oxide, 5-Undecanol Reaction Type: Photooxidation Relative Humidity: <1 Temperature: 23 Seed Name: DOS Pressure: 630

Resource type

dataset

Resource locator

https://gdex.ucar.edu/dataset/id/21f68a20-dae0-43f4-a9b1-5a7a67a4853f.html

protocol: https

applicationProfile: browser

name: ICARUS Chamber Experiment: Ziemann_20160603_Methyl nitrite/Nitric oxide/5-Undecanol_Hydroxyl radical_DOS

description: Metadata Link

function: download

Unique resource identifier

code

codeSpace

Dataset language

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

Keywords

Keyword set

keyword value

Dataset

originating controlled vocabulary

title

reference date

date type

revision

effective date

2014-10-16

Keyword set

keyword value

EARTH SCIENCE > ATMOSPHERE > AEROSOLS

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Keyword set

keyword value

Other > Physical Models > Laboratory > Laboratory

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Keyword set

keyword value

In Situ/Laboratory Instruments > Chemical Meters/Analyzers

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2016-06-03

End position

2016-06-03

Dataset reference date

date type

publication

effective date

2022-01-07

date type

modified

effective date

2022-01-07

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

Compressed Archive File (application/zip)

version of format

Constraints related to access and use

Constraint set

Use constraints

Creative Commons Attribution 4.0 International License.

Limitations on public access

These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

Responsible organisations

Responsible party

organisation name

Ziemann

email address

marla.devault@colorado.edu

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

UCAR/NCAR - GDEX

email address

gdex@ucar.edu

responsible party role

pointOfContact

Metadata date

2022-01-27T09:12:22-07:00

Metadata language