Identification

Title

ICARUS Chamber Experiment: 2014 FIXCIT Study_20140109_ISOPRENE/Nitrogen dioxide/Ozone/Formaldehyde_Nitrate radical_N/A_Isoprene + NO3/HO2, dry, no seed

Abstract

Goals: Explore products formed due to isoprene + NO3 oxidation when under conditions that are more relevant to the atmosphere (i.e., NO3 and HO2 are both present in the chamber like ambient conditions). Turn on lights to confirm the formation of nitrooxyhydroxyepoxide from OH oxidation of nitrooxyhydroperoxide. Summary: The experiment turned out well, and only a couple of instruments had an interference for formaldehyde. The NO CL monitor saw an interference and the LIF OHR saw diminished signal due to OH reacting with formaldehyde, but all other instruments ran smoothly. The LIF OHR was taken off of the experiment because the signal was too depleted to be useful. This helped save bag volume, so that the GTHOS could sample the entire experiment. Nitrooxyhydroperoxide, hydroxynitrate, and carbonylnitrate all formed in the dark and leveled off before turning on lights. When lights were turned on, nitrooxyhydroperoxide was oxidized via OH to nitrooxyhydroxyepoxide as expected. Organization: 2014 FIXCIT Study Lab Affiliation: California Institute of Technology Chamber: Seinfeld chambers Experiment Category: Gas phase chemical reaction Oxidant: Nitrate radical Reactants: ISOPRENE, Nitrogen dioxide, Ozone, Formaldehyde Reaction Type: Dark oxidation Relative Humidity: 5 Temperature: 26 Seed Name: N/A Pressure: 750

Resource type

dataset

Resource locator

https://gdex.ucar.edu/dataset/id/90563cc7-679c-484d-ae7a-a116fe882bc4.html

protocol: https

applicationProfile: browser

name: ICARUS Chamber Experiment: 2014 FIXCIT Study_20140109_ISOPRENE/Nitrogen dioxide/Ozone/Formaldehyde_Nitrate radical_N/A_Isoprene + NO3/HO2, dry, no seed

description: Metadata Link

function: download

Unique resource identifier

code

codeSpace

Dataset language

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

Keywords

Keyword set

keyword value

Dataset

originating controlled vocabulary

title

reference date

date type

revision

effective date

2014-10-16

Keyword set

keyword value

EARTH SCIENCE > ATMOSPHERE > AEROSOLS

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Keyword set

keyword value

Other > Physical Models > Laboratory > Laboratory

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Keyword set

keyword value

In Situ/Laboratory Instruments > Chemical Meters/Analyzers

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2014-01-09

End position

2014-01-09

Dataset reference date

date type

publication

effective date

2021-10-12

date type

modified

effective date

2021-10-12

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

Compressed Archive File (application/zip)

version of format

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Use constraints

Creative Commons Attribution 4.0 International License.

Limitations on public access

These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

Responsible organisations

Responsible party

organisation name

2014 FIXCIT Study

email address

tbn@ucdavis.edu

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

UCAR/NCAR - GDEX

email address

datahelp@ucar.edu

responsible party role

pointOfContact

Metadata date

2022-01-27T09:12:22-07:00

Metadata language