Identification

Title

ICARUS Chamber Experiment: Nguyen Group_20220520_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/alpha-Pinene_Nitrate radical_Ammonium sulfate

Abstract

Goals: To quantify SOA yield and gas-phase product yields (particularly of C10 nitrooxy-hydroperoxide and other organonitrates) from humid nighttime RO2+HO2-dominated NO3-initiated chemistry of a-pinene. Summary: The chamber was humidified, after which H2O2, NO2, and O3 were injected in the chamber and allowed to equilibrate, forming NO3 and HO2. Ammonium sulfate seed particles were injected. Then a-pinene was injected and decayed by simultaneous reaction with ozone and NO3. Gas phase organics were monitored by CF3O- CIMS (units: normalized counts), particle formation was monitored by SMPS, and RH/T/O3/NOx were monitored throughout. O3/NOx data sometimes require post-correction not applied here, including subtraction of an ozone interference from H2O2 (1 ppm H2O2 is detected as about 12 ppb ozone) and correction for an in-line HEPA filter (see timeline for applicable timing) that scrubs about 10% of NO2 and 45% of ozone. CIMS was periodically stopped during this experiment to retune. Organization: Nguyen Group Lab Affiliation: UC Davis Chamber: Tran's big bag of air Experiment Category: Gas phase chemical reaction, Aerosol formation Oxidant: Nitrate radical Reactants: Nitrogen Dioxide, Ammonium Sulfate, Ozone, Hydrogen Peroxide, alpha-Pinene Reaction Type: Dark oxidation Relative Humidity: 66 Temperature: 22 Seed Name: Ammonium sulfate Pressure: approx 1 atm

Resource type

dataset

Resource locator

https://gdex.ucar.edu/dataset/id/e6fd355f-104d-474e-bd35-5f104db74e9e.html

protocol: https

applicationProfile: browser

name: ICARUS Chamber Experiment: Nguyen Group_20220520_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/alpha-Pinene_Nitrate radical_Ammonium sulfate

description: Metadata Link

function: download

Unique resource identifier

code

codeSpace

Dataset language

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

Keywords

Keyword set

keyword value

Dataset

originating controlled vocabulary

title

reference date

date type

revision

effective date

2014-10-16

Keyword set

keyword value

EARTH SCIENCE > ATMOSPHERE > AEROSOLS

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Keyword set

keyword value

In Situ/Laboratory Instruments > Chemical Meters/Analyzers

originating controlled vocabulary

title

reference date

date type

revision

effective date

2018-03-15

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2022-05-20

End position

2022-05-20

Dataset reference date

date type

publication

effective date

2023-08-23

date type

modified

effective date

2023-08-23

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

Compressed Archive File (application/zip)

version of format

Constraints related to access and use

Constraint set

Use constraints

Creative Commons Attribution 4.0 International License.

Limitations on public access

These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

Responsible organisations

Responsible party

organisation name

Nguyen Group

email address

kelvinhbates@gmail.com

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

UCAR/NCAR - GDEX

email address

gdex@ucar.edu

responsible party role

pointOfContact

Metadata date

2023-08-23T02:30:01-06:00

Metadata language